Wednesday, January 29, 2020

Investigating how concentration affects rate of reaction Essay Example for Free

Investigating how concentration affects rate of reaction Essay This means that you would need to use 200ml of the original 0. 01M solution with 50ml of distilled water to make 250ml of 0. 008M solution. Remember to keep all other solutions at a constant concentration throughout. Investigat  the same range of concentrations as was used for potassium bromide, to ensure that a rate equation can easily be found. Making Required Solutions 0. 01M potassium bromate(V): KBrO3: K = 1 x 39. 1 = 39. 1 Br = 1 x 79. 9 = 79. 9 O3 = 3 x 16. 0 = 48. 0 RFM = 167 grams needed = (0. 01 x 167 x 250) 1000 = 0. 4175g dissolved in enough distilled water to make 250ml of solution. 1M Sulphuric acid: H2SO4: H2 = 2 x 1. 0 = 2 S = 1 x 32. 1 = 32. 1 O4 = 4 x 16. 0 = 64. 0 = 98. 1 grams needed = (1 x 98. 1 x 250) 1000 = 24. 525g dissolved in enough distilled water to make 250ml of solution. 0. 0001M phenol: C6H5OH: C = 6 x 12. 0 = 72. 0 H = 6 x 1. 0 = 6. 0 O = 1 x 16. 0 = 16. 0 = 94. 0 grams needed = (0. 0001 x 94 x 250) 1000 = 0. 00235g dissolved in enough distilled water to make 250ml of solution. 0. 01M potassium bromide: KBr: K = 1 x 39. 1 = 39. 1 Br = 1 x 79. 9 = 79. 9 = 119. 0 grams needed = (0. 01 x 119 x 250) 1000 = 0. 2975g dissolved in enough distilled water to make 250ml of solution. Risk Assessment (6) The following risk assessments are based on concentrated solutions of each substance. The concentrations I will be using are much more diluted that the solutions mentioned below to ensure that my experiment is safer. Although some of the acute hazards and symptoms associated with the concentrations I am using will not be as severe as those shown below, the risks are still very serious. For this reason I will still take appropriate precautions and will handle each substance with care. Potassium bromate(V): Type of Hazard Acute Hazards/Symptoms Prevention of Hazard Solving Hazard Fire. Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire. No contact with combustibles and reducing agents. Water in large amounts. Explosion Risk of fire and explosion on contact with combustible substances and reducing agents. n/a In case of fire: keep drums etc. cool by spraying with water. Inhalation Cough. Sore throat. Breathing protection. Fresh air, rest. Refer for medical attention. Contact with skin Redness. Protective gloves. First rinse with plenty of water, then remove contaminated clothes and rinse again. Refer for medical attention. Contact with eyes Redness. Pain. Safety goggles, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. Ingestion Abdominal pain. Diarrhoea. Nausea. Vomiting. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Give a mixture of activated charcoal in water to drink. Induce vomiting if person is conscious. Refer for medical attention. Spillage n/a n/a Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder then remove to safe place. Do not absorb in sawdust or other combustible absorbents. Storage n/a Separated from combustible and reducing substances, powdered metals and incompatible materials. See Chemical Dangers. n/a Sulphuric acid: Type of Hazard Acute Hazards/Symptoms Prevention of Hazard Solving Hazard Fire Not combustible. Many reactions may cause fire or explosion. Gives off irritating or toxic gases in a fire. No contact with flammable substances. No contact with combustibles. No water. In case of fire in the surroundings: powder, foam, carbon dioxide. Explosion Risk of fire and explosion on contact with bases, combustible substances, oxidants. n/a In case of fire: keep drums etc. cool by spraying with water but no direct contact with water. Inhalation Corrosive. Burning sensation. Sore throat. Cough. Struggling to breathe. Shortness of breath. Ventilation or breathing protection. Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. Contact with skin Corrosive. Redness. Pain. Blisters. Serious skin burns. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. Contact with eyes Corrosive. Redness. Pain. Severe deep burns. Face shield or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. Ingestion Corrosive. Abdominal pain. Burning sensation. Shock or collapse. Do not eat, drink, or smoke during work. Rinse mouth. Do not induce vomiting. Refer for medical attention. Spillage n/a n/a Do not absorb in saw-dust or other combustible absorbents. Personal protection: complete protective clothing including self-contained breathing apparatus. Do not let this chemical enter the environment. Storage n/a Separated from combustible and reducing substances, strong oxidants, strong bases, food and feedstuffs, incompatible materials. May be stored in stainless steel containers. Store in an area having corrosion resistant concrete floor. n/a Phenol: Type of Hazard Acute Hazards/Symptoms Prevention of Hazard Solving Hazard Fire Combustible. No open flames. No contact with strong oxidants. Alcohol-resistant foam, powder, water spray, carbon dioxide. Explosion Above 79i C explosive vapour/air mixtures may be formed. Above 79i C use a closed system, ventilation. In case of fire: keep drums etc. cool by spraying with water. Inhalation Sore throat. Burning sensation. Cough. Dizziness. Headache. Nausea. Vomiting. Shortness of breath. Laboured breathing. Unconsciousness. Avoid inhalation of fine dust and mist. Ventilation or breathing protection. Fresh air, rest. Half-upright position. Refer for medical attention. Contact with skin Easily absorbed. Serious skin burns. Numbness. Convulsion. Collapse. Coma. Death. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. To remove substance use polyethylene glycol 300 or vegetable oil. Refer for medical attention. Wear protective gloves when administering first aid. Contact with eyes Pain. Redness. Permanent loss of vision. Severe deep burns. Face shield, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. Ingestion Corrosive. Abdominal pain. Convulsions. Diarrhoea. Shock or collapse. Sore throat. Smoky, greenish-dark urine. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Give plenty of water to drink. Do not induce vomiting. Refer for medical attention. Spillage n/a n/a Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder then remove to safe place. Personal protection: complete protective clothing including self-contained breathing apparatus. Do not let this chemical enter the environment. Storage n/a Separated from strong oxidants, food and feedstuffs. Keep in a well-ventilated room. n/a Potassium bromide: The hazards for this substance are almost negligible, especially for the low concentrations that I will be using. However, protective goggles will still be worn to avoid contact with eyes, as this could cause irritation. This substance could also cause some discomfort if ingested, so I will take be very careful to ensure that this doesnt happen. Method for Investigating Temperature Change Extra Apparatus Reason For Use Size/Concentration Heating plate Used to heat the mixture to different temperatures during the reaction.n/a Beakers Used as a water bath to heat the mixtures evenly. 500ml Boiling tubes Used to hold reacting mixture whilst it is heated or cooled to the desired temperature. n/a Ice cubes Used to cool the water bath to temperatures below room temperature. n/a Thermometer Used to measure the temperature of the mixture so that it can be kept constant throughout the reaction. n/a Method 1. Set the apparatus up as was done in the experiment investigating concentration change. However, this time use a heating plate rather than a magnetic stirrer so that temperature can be adjusted. 2. Mix 5cm3 of potassium bromate(V) solution, 5cm3 of sulphuric acid solution and 5cm3 of phenol solution in a boiling tube and add 4 drops of methyl orange indicator. 3. Add 5cm3 of potassium bromide to a separate boiling tube. 4. Fill a large beaker with water and place it on top of the heating plate and set it to the required temperature. To achieve cooler temperatures put ice cubes into the beaker and monitor the temperature using a thermometer. Place the boiling tubes containing the correct solutions in the water bath so that they are also heated or cooled to this temperature. 5. Mix the two solutions and start the stopwatch. Record the time taken for the solution to go colourless. Ensure that the temperature of the water is kept constant. This can be done by having a thermometer in the beaker. Although the higher temperatures should be easily maintained by the heating apparatus, lower temperatures must be kept constant by adding more ice cubes if required. 6. Repeat 5 times with each temperature to ensure accurate and fair results. Results With Respect to Potassium Bromate(V) The table below shows my results when varying the concentration of potassium bromate(V): Concentration of Potassium Bromate(V) (mol/dm-3). Time Take For the Mixture to Turn Colourless (seconds) Repeat 1 Repeat 2 Repeat 3 Repeat 4 Repeat 5 Average Reaction Rate (seconds-1) Graph 1 on the next page shows the concentration of potassium bromate(V) plotted against the average time taken for the solution to turn colourless. From this graph I can see that there is a negative correlation because as concentration is increased, the time taken for the solution to turn colourless decreases. However, this graph does not provide enough information to work out the rate equation data for potassium bromate(V). For this, I had to draw up a graph of concentration against reaction rate. Reaction rate is worked out using the following equation: Reaction Rate = 1 Time This is presented in Graph 2. Graph 2 has a line of best fit which is a straight diagonal line, rather than a curve. It also shows that there is a positive correlation between concentration and reaction rate, as when concentration of potassium bromate(V) is increased, reaction rate increases. I could draw the line of best through the origin at point (0,0) as I know that if the concentration is 0M then the reaction will not occur the reaction rate will be 0seconds-1 (this can be applied to all other graphs of concentration against reaction rate that I have drawn). I decided to draw the majority of my graphs using a computer to plot the axes and points, and drawing the line or curve of best fit by hand. The computer can provide better accuracy than I can as far as drawing the axes and plotting the points is concerned. However, I believe that I can provide more accuracy when drawing the line or curve of best fit. My line of best fit suggests that the reaction, with respect to potassium bromate(V), is first order. This means that that rate equation so far is as follows: Rate = k[BrO3] Results With Respect to Potassium Bromide The table below shows my results when varying the concentration of potassium bromide: Concentration of Potassium Bromide (mol/dm-3) Time Take For the Mixture to Turn Colourless (seconds) Repeat 1 Repeat 2. Repeat 3 Repeat 4 Repeat 5 Average Reaction Rate (seconds-1) The line of best fit is once again a straight diagonal one. This shows that there is again a positive correlation between concentration and reaction rate.

Tuesday, January 21, 2020

The Hiding Place by Orna Jagur Essay -- Hiding Place Orna Jagur Essays

The Hiding Place by Orna Jagur   Ã‚  Ã‚  Ã‚  Ã‚  The Hiding Place is about Corrie ten Boom, her family, and how they helped the Jews in Holland when Germany invaded Holland in World War II. The main characters are Corrie, her older sisters Betsie and Nollie, her older brother Willem, and their father, Casper ten Boom, commonly referred to as Opa. The book starts out in January of 1937, in Haarlem, Holland.   Ã‚  Ã‚  Ã‚  Ã‚  When Germany invaded Holland during the beginning of World War II, the Jews were the German soldiers and Adolf Hitler’s main targets. Jews were required to wear a yellow star on their shirt, and if they walked around town during the day, they risked being taken into captivity by the German soldiers. This, among other racism against the Jews, infuriated Corrie and her family. If a person was caught helping to hide a Jew, they were also taken into captivity. Corrie and her family didn’t care if they’d ever get caught. Her father once said, â€Å"I’d consider it an honor to give my life for just one of God’s chosen people.† Also, some of Corrie’s dearest friends were Jews, and she wanted nothing but to keep them safe and away from harm. During the course of World War II, Corrie and her family were part of the â€Å"Dutch Underground,† a secret widespread group of people that would help to hide Jews and their families from the German soldiers. Corrie’s family’s house was the center of the â€Å"Dutch Underground.† They had secret city-affiliated people that would help them with it, suc...

Monday, January 13, 2020

Central Dogma Paper

The Central Dogma of Molecular Biology was founded by Francis Crick in 1958. A central dogma of biology provides an explanation as to how gene expression occurs. The central dogma is the main thesis of molecular inheritance. It states that DNA makes RNA, which makes protein. Genes control the traits by controlling which proteins are made. The process of Central Dogma of Molecular Biology is when DNA transcripts into RNA and then translates into protein. Transcription is the transfer of genetic information from DNA forming into RNA.The differences between DNA and RNA are the sugar that’s in DNA which is called deoxyribose and ribose for RNA which does not have sugar. When DNA replication begins, it begins at a specific point in the DNA molecule called the origin of replication site. The enzyme helicase unwinds and separates a portion of the DNA molecule. After the DNA polymerase separates a portion of the molecule it then initiates the process of replication in which DNA polyme rase can add new nucleotides to a pre-existing chain of nucleotides.Therefore, replication begins as an enzyme called primase and it assembles an RNA primer at the origin of the replication site. The RNA primer consists of a sequence of RNA nucleotides, complementary to a section of the DNA strand that is being prepared for replication. The RNA primer is then removed and replaced with a sequence of DNA nucleotides. Then Okazaki fragments are synthesized and the RNA primers are replaced with DNA nucleotides and the individual Okzaki fragments are bonded together into a continuous complementary strand.During transcription deoxyribose nucleic acid is formed into another nucleic acid which is ribonucleic acid or RNA. Transcription begins when RNA polymerase binds onto the double stranded DNA molecule. RNA polymerase moves along the strand of DNA making a complementary single stranded RNA molecule. Here’s a good thing you could remember, take the root word ‘scribe’ ou t of transcription and think of it was a person who writes copies of important documents because that is what scribe means.Next is translation, it is the process of using the code in RNA to put together the protein and translation is a word that describes the transfer of information from one to another. Translation begins when messenger RNA binds to the ribosome. The RNA passes along the ribosome and brings out 3 nucleotides at a time. While that’s happening the amino acid that is being carried is also being transferred to the amino acid chain. After that is done the ribosomal complex falls apart and the protein is released into a cell.During protein synthesis, amino acids build a protein molecule that’s, of course, called protein synthesis. Synthesis means ‘putting together’, so that is a good way to remember protein synthesis. Protein synthesis is the cellular process of building proteins. Translation has a part of the central dogma that is also included in protein synthesis and transcription is not. Translation is just the decoding of RNA to make a chain of amino acids that will then, later, turn into protein. Overall in central dogma, DNA is simply the instructions to making proteins.

Sunday, January 5, 2020

Freedom of the Press Versus Right to Privacy - 932 Words

Freedom of the press versus right to privacy ByRobert Skidelsky (China Daily) Privacy has become a big issue in contemporary jurisprudence. The right to privacy is enshrined in the United Nations Declaration of Human Rights, and guaranteed by Article 8 of the European Convention on Human Rights. But Article 8 is balanced by Article 10, which guarantees free expression of opinion. So what right has priority when they conflict? Under what circumstances, for example, is it right to curtail press freedom in order to protect the right to privacy, or vice versa? The same balance is being sought between the right of citizens to data privacy and government demands for access to personal information to fight crime, terrorism, and so on.†¦show more content†¦A law that curtails the abuse of press power while protecting its freedom to expose the abuse of political power would be difficult, but not impossible, to frame. The essential principle is that the media should not be allowed to pander to the public s prurience under cover of protecting the public interest. What famous people - indeed ordinary people, too - do in private should be off limits to the media unless they give permission for those activities to be reported, photographed, or filmed. The only exceptions would be if a newspaper has reasonable grounds for believing that the individuals concerned are breaking the law, or that, even if they are not breaking the law, they are behaving in such a way as to render them unfit to perform the duties expected of them. Thus, a pop star s consumption of illegal drugs may be reported, but not his or her sexual habits (if they are legal). The private life of a politician may be revealed if it is expected to have consequences for the way the country is being governed; that of a top executive of a public company if it may affect the returns to shareholders. 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